Electrical Resistivity Imaging of a Permanganate Injection During In Situ Treatment of RDX‐Contaminated Groundwater

Groundwater beneath the former Nebraska Ordnance Plant (NOP) is contaminated with the explosive hexahydro‐1,3,5‐trinitro‐1,3,5‐triazine (RDX) and trichloroethene (TCE). Previous treatability experiments confirmed that permanganate could mineralize RDX in NOP aquifer material. The objective of this study was to determine the efficacy of permanganate to transform RDX in the field by monitoring a pilot‐scale in situ chemical oxidation (ISCO) demonstration. In this demonstration, electrical resistivity imaging (ERI) was used to create two‐dimensional (2‐D) images of the test site prior to, during, and after injecting sodium permanganate. The ISCO was performed by using an extraction‐injection well configuration to create a curtain of permanganate. Monitoring wells were positioned downgradient of the injection zone with the intent of capturing the permanganate‐RDX plume. Differencing between ERI taken preinjection and postinjection determined the initial distribution of the injected permanganate. ERI also quantitatively corroborated the hydraulic conductivity distribution across the site. Groundwater samples from 12 downgradient wells and 8 direct‐push profiles did not provide enough data to quantify the distribution and flow of the injected permanganate. ERI, however, showed that the permanganate injection flowed against the regional groundwater gradient and migrated below monitoring well screens. ERI combined with monitoring well samples helped explain the permanganate dynamics in downgradient wells and support the use of ERI as a means of monitoring ISCO injections.     

The exchange of fluid mass between quasi-geostrophic and ageostrophic motions during the reflection of Rossby waves from a coast. I. The case of an infinite rectilinear coast

When the problem of the reflection of spatially localized Rossby waves from a coast is treated using the quasigeostrophic (QG) approximation, the total fluid mass and the along-shore circulation calculated from the geostrophic height field are not conserved. To understand the correct mass balance and the degree to which the QG equations and boundary conditions may be in error, we analyze an initial-value problem for the Laplace tidal equations on a β-plane in the asymptotic limit 1, where is the ratio of the spatial scale of the motion to the Earth's radius.It is shown that there is a coupling between QG and O() fields. Physically, the coupling occurs by a peculiar adjustment process in the O() approximation in which fast gravity waves are permanently generated to build up a quasi-stationary edge Kelvin wave. Different temporal scales (large for O(1) Rossby waves and small for the O() gravity waves make comparable the contributions of the waves to the mass and circulation balance equations. However, QG analysis itself describes the reflection of Rossby waves correctly, but is incomplete, and for satisfactory balances one has to take into account the fields of both orders of the approximation.Applications of the results to closed basins, baroclinicity, and variable bottom topography are discussed. It is conjectured that an interaction of strong oceanic eddies with a coast (continental slope) may give rise to noticeable along-shore jet currents.     

Influence of aquifer heterogeneity and return flow on pumping test data interpretation

Analytical solutions of drawdown in unconfined aquifers are widely applied for determining the specific yield, S_y, and the horizontal and the vertical hydraulic conductivity K_r and K_z, respectively. In many previous studies, estimates of S_y and K_z were observed to be highly variable and physically unrealistic. This has been attributed to the conceptualization of flow above the declining water table and aquifer heterogeneity in the applied models. We present the analysis of time-drawdown data from a pumping test instrumented with depth-differentiated observation piezometers arranged in clusters. Applying homogeneous anisotropic aquifer models in combination with nonlinear least squares parameter identification techniques, the data were analyzed in different groups: analysis of data from individual piezometer clusters and simultaneous analysis of the entire data set from all piezometer clusters (global analysis). From the cluster analyses, estimates of S_y and K_z exhibit large variances and depart from a priori estimates inferred from the hydrostratigraphy. Parameter estimates from the global analysis do not fall within the parameter bounds (minimum and maximum values) defined by the cluster analyses. While heterogeneity appears to be the important reason for large parameter variances, we discuss the influence of rarely considered aquifer return flow on drawdown and the inconsistent results from the cluster and global analyses. We corroborate our findings with data on hydraulic gradients, slug test data, and results from the application of a more realistic numerical flow model.     

Removal of Cryptosporidium parvum Oocysts by Rapid Sand Filtration with Ballasted Flocculation‐Filtration and Intermediate Downwashes

A novel and efficient protocol optimising deep‐bed filtration of surface water was developed. The innovation lies in ballasted‐flocculation filtration and an intermediate downwash. The approach is based on the assumption that kaolin particles with a partial positive charge may adsorb onto the surface of C. parvum oocysts and neutralize their negative charge. Application of this technology enhanced removal of inorganic particles and Cryptosporidium parvum oocysts by approximately 30 % and shortened the ripening stage of the filtration process from 1 h to about 10 min.     

Infrared photometric properties of inner and outer parts of HⅡ regions

The fact that infrared ring nebulae(IRRNe) are frequently associated with HⅡ regions provides us with an opportunity to study dust at the interface between ionized and neutral gas. In this paper, we analyze the associated infrared(IR) radiation in the range from 8 to 500 μm in the outer and inner parts of32 IRRNe showing a round shape. We aim to determine the morphology of these objects and possible dust evolution processes based on comparing IR radiation towards the ionized and neutral regions. We calculate six slopes between adjacent wavelengths in their spectral energy distributions to trace the difference in physical conditions inside and outside the ionized regions. Using data on these 32 objects, we demonstrate that their morphology is likely 3 D spherical rather than 2 D plane-like. The slope between 70 and 160 μm is the most appropriate tracer of dust temperature in the outer envelope. The larger 8-to-24 μm intensity ratio is associated with smaller intensities at mid-IR, indicating that polycyclic aromatic hydrocarbons(PAHs) may indeed be generated due to larger grain destruction. These data are important for the subsequent theoretical modeling, and determining the dust evolution in HⅡ regions and their envelopes.     

Classification and delineation of groundwater–lake interactions in the Nebraska Sand Hills (USA) using electrical resistivity patterns

Lake?Cgroundwater interactions exhibit a complex three-dimensional (3D) structure that is seldom studied. The utility of waterborne electrical resistivity (ER) surveys is explored for characterization of 3D groundwater flow and solute transport patterns for three lakes in the Nebraska Sand Hills, USA. Waterborne ER surveys, using contrasts between lake and groundwater solutes as natural tracers, are useful for inferring 3D patterns of groundwater flow and solute transport as well as classifying groundwater?Clake interactions. Three unique groundwater flow systems are interpreted under each lake from dense networks of two-dimensional (2D) waterborne ER surveys. A lateral transition from high to low ER values beneath the saline Wilson Lake expresses its flow-through regime, where groundwater salinity indicates changes from groundwater inflow to outflow. Alkali Lake ER profiles reveal a prevalent ER increase with depth over the lakebed area that is characteristic of groundwater discharge lakes. ER profiles beneath Gimlet Lake are the most resistive and indicate pockets of high ER related to fresh groundwater discharge into the lake, supporting a flow-through regime with a short flushing time. These ER patterns correctly classify groundwater?Clake interactions and provide high spatial resolution of mixing patterns for systems with varying water salinity.     

Effects of Multiscale Anisotropy on Basin and Hyporheic Groundwater Flow

Various subsurface flow systems exhibit a combination of small‐scale to large‐scale anisotropy in hydraulic conductivity (K). The large‐scale anisotropy results from systematic trends (e.g., exponential decrease or increase) of K with depth. We present a general two‐dimensional solution for calculation of topography‐driven groundwater flow considering both small‐ and large‐scale anisotropy in K. This solution can be applied to diverse systems with arbitrary head distribution and geometry of the water table boundary, such as basin or hyporheic flow. In a special case, this solution reduces to the well‐known Tóth model of uniform isotropic basin. We introduce an integral measure of flushing intensity that quantifies flushing at different depths. Using this solution, we simulate heads and streamlines and provide analyses of flow structure in the flow domain, relevant to basin analyses or hyporheic flow. It is shown that interactions between small‐scale anisotropy and large‐scale anisotropy strongly control the flow structure. In the classic Tóth flow model, the flushing intensity curves exhibit quasi‐exponential decrease with depth. The new measure is capable of capturing subtle changes in the flow structure. Our study shows that both small‐ and large‐scale anisotropy characteristics have substantial effects that need to be integrated into analysis of topography‐driven flow.     

Geological structure, composition of ores and age of the Bamsk gold deposit, Amur region, Russia

The Bamsk gold-ore deposit is located in the Amur region, the Far East of Russia. It is confined to the Early Cretaceous volcanicoplutonic uplift of central type, located in the Stanov folded-clumpy Pre-Cambrian system. The deposit is presented by a series of gold-bearing quartz and carbonate-quartz vein-stringer zones. They are confined to the super-intrusive zone of the Nevachansk subvolcanic intrusion of sienite-porphyric composition. The mineralization is being controlled by zone of fractures developed in the autochthone of the Bamsk fault. Quartz, carbonates and sericite prevail in the composition of ores. The quantity of ore minerals doesn‘t exceed 1% ～ 5%. Pyrite, chalcopyrite, galena and native gold are widely spread, Sheelite, gold and silver tellurides, sulphobismuthites, acanthite, sphalerite and cinnabar are less developed. Four stages of mineralization have been distinguished. Gold-sulphide-sulphosalt ore with tellurides of gold and silver is productive for gold. The following set of elements is typomorphic for the ores of the deposit: Au, Ag, Cu, Bi, Mo, Pb and Sb (W1, Pb1, Mo) -Cu- (Ag, Bi, Sb, Mn, W2,, Pb2) form the vertical series of zoning. Rocks, enclosing the mineralization are exposed to the processes of listvenitization-beresitization. The processes of gumbeization and argillization are less manifested. The age of the gold mineralization, determined by Rb-Sr method on ore-accompanying minerals, is 130.6 Ma.